Accurate Control of Chain Ends by a Novel "Living" Free-Radical Polymerization Process
β Scribed by Hawker, Craig J.; Hedrick, James L.
- Book ID
- 121016556
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 297 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
Free radical ring-opening polymerization of 2-methylene-1,3-dioxepane (MDP) in the presence of 2,2,6,6-tetramethyl-1-piperidinyloxy free radical (TEMPO) has been achieved to afford a chain polyester (PMDP) with di-t-butyl peroxide (DTBP) as an initiator at 125ΠC. The polydispersity of the polymers d
Radical polymerization of 2-, 3-, and 4-methylstyrenes (MeSts) was investigated with benzoyl peroxide (BPO) as an initiator, in the presence of 4-methoxy-2,2,6,6tetramethylpiperidine-1-oxyl (MTEMPO). The polymerization was performed in bulk for 3.5 h at 95ΠC, and then continued for a defined time at