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Accessing the Chain Length Dependence of the Termination Rate Coefficient for Disparate Length Radicals via Reversible Addition Fragmentation Chain Transfer Chemistry: A Theoretical Study

✍ Scribed by Lovestead, Tara M.; Theis, Alexander; Davis, Thomas P.; Stenzel, Martina H.; Barner-Kowollik, Christopher


Book ID
126911117
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
123 KB
Volume
39
Category
Article
ISSN
0024-9297

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Accessing Chain Length Dependent Termina
✍ Geoffrey Johnston-Hall; Alexander Theis; Michael J. Monteiro; Thomas P. Davis; M 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB

## Abstract **Summary:** The RAFT‐CLD‐T methodology is demonstrated to be not only applicable to 1‐substituted monomers such as styrene and acrylates, but also to 1,1‐disubstituted monomers such as MMA. The chain length of the terminating macromolecules is controlled by CPDB in MMA bulk free radica