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Accessing the amide functionality by the mild and low-cost oxidation of imine

✍ Scribed by Magdi A. Mohamed; Ken-ichi Yamada; Kiyoshi Tomioka

Book ID: 104096359
Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 706 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.02.174

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✦ Synopsis

Oxidation of imines using sodium chlorite under buffered conditions gave the corresponding amides in good to high yield. The reaction was generally fast and was completed within 5-40 min. As has been established in the corresponding oxidation of aldehyde, so-called Pinnick oxidation, the good functional group tolerance and the use of inexpensive reagents are the advantages of this protocol.

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