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Access to the noryohimban [6,5,6,5,6] ring system via an intramolecular furan Diels–Alder reaction

✍ Scribed by Demosthenes Fokas; Jean E. Patterson; Gregory Slobodkin; Carmen M. Baldino

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
170 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Polycyclic indolic compounds containing the [6,5,6,5,6] ring system were prepared via an intramolecular furan Diels-Alder reaction of a,b-unsaturated amides generated by the N-acylation of 1-(2-furyl)-b-tetrahydrocarbolines. This chemistry can provide access to D( 14)-noryohimban derivatives by exploiting the functionality on the C,D,E ring system of the corresponding cycloadducts.

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