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Acceleration of the pseudorotation rates in pentacoordinated phosphorus compounds. Conformational transmission versus hexacoordinated zwitterionic intermediates

✍ Scribed by De Keijzer, A. E. H.; Buck, H. M.


Book ID
126070104
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
597 KB
Volume
53
Category
Article
ISSN
0022-3263

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A kinetic study of the alkaline hydrolys
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## Abstract It can be shown that alkaline hydrolysis of four‐coordinated phosphorus (P^IV^) compounds is substantially accelerated if the trigonal‐bipyramidal (TBP) five‐coordinated phosphorus (P^V^) intermediate in the reaction can exhibit conformational transmission. With the compounds 5a‐c, it w