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Acceleration of the methyl migration reaction with proton acids

โœ Scribed by Butts, Susan Beda.; Richmond, Thomas G.; Shriver, Duward F.


Book ID
126041490
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
369 KB
Volume
20
Category
Article
ISSN
0020-1669

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Kinetic studies established that the monomethylation of a primary amine leads to significantly higher reaction rates with glycidyl ethers. The relative rates for approximately 25 amines were determined in an alcohol solvent under pseudo-firstorder conditions (excess epoxy). The rates were referenced