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Accelerated physical ageing of thin glassy polymer films: evidence from gas transport measurements

โœ Scribed by P.H. Pfromm; W.J. Koros


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
812 KB
Volume
36
Category
Article
ISSN
0032-3861

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Through time-dependent gas transport properties, we have investigated the physical aging process of amorphous glassy polymer films made from a polynorbornene. By combining the concepts of free volume and the kinetic theory of glass stabilization, it was found that the time dependence of the gas perm