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Accelerated Hydrolysis of p-Nitrophenyl Picolinate Catalyzed by Metallomicelle Made from a Novel Macrocyclic Polyamine Copper(II) Complex

✍ Scribed by Xing-Ming Kou; Guo-Po Zhao; Zhong Huang; Yu-Hua Tian; Xiang-Guang Meng; Xian-Cheng Zeng


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
107 KB
Volume
25
Category
Article
ISSN
0256-7660

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πŸ“œ SIMILAR VOLUMES


Metallomicelle catalysis: Hydrolysis of
✍ Weidong Jiang; Bin Xu; Jianzhang Li; Qi Lin; Xiancheng Zeng; Hua Chen πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 287 KB

## Abstract Two Schiff base cobalt(II) complexes containing crowned substituents have been synthesized and employed to promote the hydrolysis of __p__‐nitrophenyl picolinate (PNPP) in a buffered micellar solution formed by a cationic Gemini surfactant, bis(hexadecyldimethylammonium)hexane bromide (

Metallomicellar Catalysis Hydrolysis of
✍ Cheng Siqing; Zeng Xiancheng; Meng Xiangguang; Yu Xiaoqi πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 142 KB

The ternary complex kinetic model for metallomicellar catalysis has been proposed in this paper. The catalytic effects of bivalent metal ion (Cu(2+), Zn(2+), and Ni(2+)) complexes of long alkyl pyridine ligands upon the hydrolysis of p-nitrophenyl picolinate (PNPP) have been studied kinetically in a