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ACC-Oxidase like activity of a copper (ii)–ACC complex in the presence of hydrogen peroxide. Detection of a reaction intermediate at low temperature

✍ Scribed by Ghattas, Wadih; Gaudin, Christian; Giorgi, Michel; Rockenbauer, Antal; Simaan, A. Jalila; Réglier, Marius

Book ID: 111973912
Publisher: Royal Society of Chemistry
Year: 2006
Tongue: English
Weight: 257 KB
Volume: 9
Category: Article
ISSN: 1359-7345
DOI: 10.1039/b515374c

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the radical oxy-Cope rearrangement. [17] For this purpose, the sulfoxide 10 was prepared from norbornenone 8 via the allylic alcohol 9 (the direct synthesis with the procedure of Evans et al. does not work in this particular case). By treating the sulfoxide 10 with Bu 3 SnH and azobisisobutyronitril