✦ LIBER ✦
Absorption spectrum of flexible conjugated polymers: the weak-disorder limit
✍ Scribed by Z.G. Soos; K.S. Schweizer
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 406 KB
- Volume
- 139
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Purely conformational contributions to dipole transition moments lead to a general new expression for the absorption spectrum offlexible conjugated polymers with persistence length <, and alternation 6. Blue-shifts are found at rod-to-coil transitions without invoking rotational defects that break the conjugation. Conformational coupling in the weak-disorder limit increases the effective