Alkyl and alkylperoxy radicals originating from dimethyl ether have been studied in the gas phase at 296 K. A pulse radiolysis-UV absorption technique was used. Absorption cross-sections were quantified over the wavelength range 220-350 nm. At 230 nm, O'cH3oclJ2 = (4.2 + 0.5)× 10 -18 cm 2 molecule-l
✦ LIBER ✦
Absorption Spectrum and Absolute Absorption Cross Sections of CH 3 O 2 Radicals and CH 3 I Molecules in the Wavelength Range 7473–7497 cm –1
✍ Scribed by Faragó, Eszter P.; Viskolcz, Bela; Schoemaecker, Coralie; Fittschen, Christa
- Book ID
- 121398363
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 941 KB
- Volume
- 117
- Category
- Article
- ISSN
- 1089-5639
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The absolute UV absorption cross sections of CF3CC1202, CFJCHF02, CFC12CH202, and CFZCICH20, have been measured in the gas phase at 298 K in the range 200-290 nm using the flash-photolysis technique. CF,COCl has been identified as a product in the system involving the self-reaction of CF$C1202.