Absorption Spectra of Substances containing Alkyl Radicals
β Scribed by THOMPSON, H. W.; FREWING, J. J.
- Book ID
- 109510075
- Publisher
- Nature Publishing Group
- Year
- 1935
- Tongue
- English
- Weight
- 226 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/135507a0
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Alkyl, (CH3)3COC(CH3)2CH2, and alkyl peroxy, (CH3)3COC(CH3)2CH202, radicals from di-tert-butyi ether (DTBE), have been studied in the gas phase at 296 K. A pulse radiolysis UV absorption technique was used to measure the spectra and kinetics. Absorption cross sections were quantified over the wavele
Alkyl and alkyl peroxy radicals from t-butyl alcohol (TBA), HOC(CH,),CH; and HOC(CH9)&H20i have been studied in the gas phase at 298 K. Two techniques were used: pulse radiolysis UV absorption to measure the spectra and kinetics, and long path-length Fourier transform infrared spectroscopy (FTIR) to