## Abstract For Abstract see ChemInform Abstract in Full Text.
Absolute stereochemistry of the diepoxins
โ Scribed by Gerhard Schlingmann; Stefan Matile; Nina Berova; Koji Nakanishi; Guy T. Carter
- Book ID
- 103401591
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 614 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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๐ SIMILAR VOLUMES
The CD exciton chirality method was applied to determine the absolute stereochemistry of the strevertenes, antifungal pentaene macrolides produced by Streptoverticillium sp. LL-30F848. The CD difference spectrum of strevertene A methyl ester 15-dimethylaminobenzoate showed a positive couplet between
## Summarv: The configuration at C-4 of the novel casbenoid diterpene, crotonitenone (3), was determined by Horeau's method as (R) -hence the absolute stereochemistry
In the course of a study of the sesquiterpenes of the leaf oil of Alaska Cedar (Chamaecy-Paris nootkatensis) 1 we encountered a levorotatory calamenene which was clearly a mixture of the cis-and trans-isomer by NMR (see Figure ). -This mixture could not be resolved into its components by any of si