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Absolute stereochemistry of keramaphidin B

โœ Scribed by Jun'ichi Kobayashi; Naoko Kawasaki; Masashi Tsuda

Book ID
103407927
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
125 KB
Volume
37
Category
Article
ISSN
0040-4039

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Absolute stereochemistry at C-15 in penaresidins A (1) and B (2) was established to be S on the basis of I H NMR data of the tri-O-MTPA esters, indicating that the absolute configurations of 1 and 2 are 2S, 3R, 4S, 15S (1 and 2), and 16S (1).