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Absolute Reaction Rate of Chlorine Atoms with Chloroiodomethane

โœ Scribed by Kambanis, Kyriakos G.; Argyris, Dimitris Y.; Lazarou, Yannis G.; Papagiannakopoulos, Panos

Book ID
125985616
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
65 KB
Volume
103
Category
Article
ISSN
1089-5639

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Absolute reaction rate of chlorine atoms
Absolute reaction rate of chlorine atoms with neopentane
โœ Kyriakos G. Kambanis; Yannis G. Lazarou; Panos Papagiannakopoulos ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 414 KB

The reaction of atomic chlorine with neopentane was studied in the gas phase with the Very Low Pressure Reactor (VLPR) technique over the temperature range 273-333 K. The absolute reaction rate was found to be temperature-independent, and the average rate constant was kl = (1.11 5 0.13) X cm3 molecu

Temperature dependence of the rate coeff
Temperature dependence of the rate coefficients for the reaction of chlorine atoms with chloromethanes
โœ John J. Orlando ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 192 KB ๐Ÿ‘ 2 views

Rate coefficients for the reaction of Cl atoms with CH 3 Cl (k 1 ), CH 2 Cl 2 (k 2 ), and CHCl 3 (k 3 ) have been determined over the temperature range 222-298 K using standard relative rate techniques. These data, when combined with evaluated data from previous studies, lead to the following Arrhen