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Absolute Rate Constants for Collisional Vibrational Relaxation in Dense Vibrational Regions of S 1p -Difluorobenzene †

✍ Scribed by Stone, Todd A.; Parmenter, Charles S.

Book ID
125945029
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
100 KB
Volume
106
Category
Article
ISSN
1089-5639

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✍ Millard H. Alexander 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 525 KB

Fully converged quantum cross sections for 4He-D2 (u= l,i=O) vibrational reliaxation were determined using the coupled-states method and a modikied version of the Gordon-Secrcst surface. First-order forbidden rotational transitions play a si@fkant role, comparable to that observed previously for the