Absolute kinetics of phenylchlorocarbene CH insertion reactions
✍ Scribed by Robert A. Moss; Shunqi Yan
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 232 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Absolute rate constants, activation parameters, a kinetic isotope effect, and hybrid density functional theory computational results are presented for various C-H insertion reactions of PhCCI.
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## Phenylchlorocarbenes , produced by photolysis of the parent diazirines, have a very limited lifetime in alkane solvents. The rate of dibappearance of p-methyl-and p-chlorophenylchlorocarbenes has been measured in iso-octane, cyclohexane and n-hexane as well as in benzene for comparison. The rat
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