Using a high-pressure \(\times\) path length sample of ozone it has been possible to record at high resolution ( \(0.006 \mathrm{~cm}^{-1}\) ) the \(3-\mu \mathrm{m}\) absorption region of this molecule. A thorough analysis of the spectra has been performed allowing one to assign for the first time
Absolute Intensities of the ν1 and ν3 Bands of 16O3
✍ Scribed by C. Claveau; C. Camy-Peyret; A. Valentin; J.-M. Flaud
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 335 KB
- Volume
- 206
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
New experimental data on the ν 1 and ν 3 bands of 16 O 3 improving the value of absolute line intensities have been obtained. The intensities of 295 lines have been measured with an average accuracy between 2.5% and 3% and the rotational expansion of the transition moment operators for the ν 1 and ν 3 bands has been deduced. Finally, a complete listing of line intensities has been computed with an intensity cutoff of 1 × 10 -25 cm -1 /molecule cm -2 .
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