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Absolute cross sections for the formation of CN(X, v = 0) produced by controlled electron impact on BrCN and CH3CN

✍ Scribed by Hirofumi Kawazumi; Teiichiro Ogawa


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
349 KB
Volume
140
Category
Article
ISSN
0009-2614

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✦ Synopsis


The absolute cross section for the electron-impact formation of a radical fragment is determined by measuring its laser-induced fluorescence in comparison with that of N:(X, v=O); cross sections for CN(X, u=O) from BrCN and CHsCN are 5.5~ lo-" cm' and 8.5 x IO-" cm', at 200 eV, respectively. The rotational temperatures of CN(X, u=O) from both molecules are 1OOOOf 4000 K, assuming a Boltzmann distribution.