Absolute configurations of the naturally occurring hydroxycitric acids
β Scribed by Jenny Pickworth Glusker; Jean A. Minkin; Carol Ann Casciato; Frederic B. Soule
- Book ID
- 118846648
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 274 KB
- Volume
- 132
- Category
- Article
- ISSN
- 0003-9861
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## Abstract The absolute configurations of three 6,7βoxygenated acetylenic spiroacetal enol ethers were determined by using the kinetic method of Horeau. The results were confirmed by the circular dichroism of the compounds in correlation with the corresponding 6,7βepoxide.
A&r,& -The underground parts of Artemisia selengensis afforded a new Cl4 acotylenic six-ring epiroketal enol ether epoxide. A closely related diastereomeric compound has been isolated previously, however, the relative configuration of the epoxy ring (anti or syn to a reference oxygen) could not be e