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Absolute Configuration of the Fungal Metabolite Spirolaxine

✍ Scribed by Adriana Bava; Marco Clericuzio; Giuseppe Giannini; Luciana Malpezzi; Stefano Valdo Meille; Gianluca Nasini

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 135 KB
Volume: 2005
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200400902

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Chiral column liquid chromatography and enantiospecific enzymatic hydrolysis were utilized to separate the enantiomers of ␣and ␤-dihydrotetrabenazine and ␣-9-O-desmethyldihydrotetrabenazine, three benzo[a]quinolizines derived from the amine-depleting drug tetrabenazine. An X-ray crystal structure an