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Absolute configuration of some benzomorphan analgetics and related compounds

✍ Scribed by Casy, Alan F.; Parulkar, Anilkumar P.

Book ID
120880587
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
361 KB
Volume
12
Category
Article
ISSN
0022-2623

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The absolute configuration of cuauhtemon
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The absolute configuration of cuauhtemone, a eudesmane-type sesquiterpene isolated from Pluchea species (Asteraceae), has been revised from 1 to 2 by chemical correlation with (R)-(+)-2-methyl-1,2-butanediol 3 through the naturally occurring 2,3-epoxy-2-methylbutanoate derivative 4. The relative ste