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Absolute Configuration of a Substituted Cyclohexanol

โœ Scribed by Linden, A. ;Stanchev, S.


Book ID
114511973
Publisher
International Union of Crystallography
Year
1995
Tongue
English
Weight
313 KB
Volume
51
Category
Article
ISSN
0108-2701

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Absolute Configuration of 3-Substituted
โœ Jakob Boelsterli; Ursula Eggnauer; Esteban Pombo-Villar; Hans-Peter Weber; Malco ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 396 KB

The l-azabicyclo[2.2. I]heptan-3-exo-ol (2) was resolved by fractional crystallisation of its hydrogen tartrate salts. The enantiomers (+)-and (-)-2 were oxidised to the ketones (-)-4 and (+)-4, respectively (Scheme). CD spectroscopy suggested that (-)-4 possesses the (IR,4S)-configuration. This abs