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Absolute configuration and anisotropic polarizability of molecules. 3. Determination of polarizability ellipsoids of the C=C bond and the cyclobutane ring in molecules of the pinene series

✍ Scribed by S. G. Vul'fson; V. F. Nikolaev

Book ID
112449947
Publisher
Springer
Year
1981
Tongue
English
Weight
377 KB
Volume
30
Category
Article
ISSN
1573-9171

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The third order electric palarizability r of the HZ-molecule and of C-C 2nd C-H a-type bonds is calculated using a vnriational-perturbation procedure; the sign, msgnitudc and anisotropy of y nre given. In the case of the Hz-molecule the influence of the choice of the wavefunction on the value ofr is