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Absolute Asymmetric Synthesis of Tertiary α-Amino Acids

✍ Scribed by Thi Thoa Mai; Dr. Mathieu Branca; Didier Gori; Dr. Régis Guillot; Prof. Cyrille Kouklovsky; Dr. Valérie Alezra

Book ID
111999996
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
584 KB
Volume
124
Category
Article
ISSN
0044-8249

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Catalytic, asymmetric synthesis of α,α-d
Catalytic, asymmetric synthesis of α,α-disubstituted amino acids
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Copper(salen) complex 1 has been found to catalyse the asymmetric alkylation of enolates derived from a variety of amino acids. There is a clear relationship between the size of the side chain in the substrate and the enantioselectivity of the process, so that the enantioselectivity decreases in the