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Absolute Asymmetric Synthesis: A Commentary

✍ Scribed by Kurt Mislow

Book ID
101946244
Publisher
John Wiley and Sons
Year
2003
Weight
65 KB
Volume
34
Category
Article
ISSN
0931-7597

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Asymmetric synthesis and absolute stereo
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✍ Jack Deeter; Jeff Frazier; Gilbert Staten; Mike Staszak; Leland Weigel πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 331 KB

Reduction of 3-(dialkylamino)-1-aryl-t-propanones with a 2:l complex of [(2R,3S-(+)-4--dimethylamino-1,2-diphenyl-3-methyl-2-butanol] (8) and lithium aluminum hydride (LAH) provided the corresponding 1,Saminoalcohols in high ee's (SO-88%). This process was developed and applied to the synthesis of L