## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
β¦ LIBER β¦
Absolute Asymmetric Photochemistry Using Spontaneous Chiral Crystallization
β Scribed by Masami Sakamoto
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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Due to the matrix effect of the crystal lattice, irradiation of alcohol 2 could be produced, depending on which enantiomorphic form of the chiral crystal was irradiated. As ketone 1 yields 2 diastereoselectively as the main product (97% de). Furthermore, the chiral crystal environment in the ketone