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Absolute Asymmetric Photochemistry Using Spontaneous Chiral Crystallization

✍ Scribed by Masami Sakamoto


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Spontaneous Chiral
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Due to the matrix effect of the crystal lattice, irradiation of alcohol 2 could be produced, depending on which enantiomorphic form of the chiral crystal was irradiated. As ketone 1 yields 2 diastereoselectively as the main product (97% de). Furthermore, the chiral crystal environment in the ketone