Semiempirical PM3-RHF-CI calculations were used to probe structure-exchange coupling relationships in radical-substituted Zn(II) porphyrins. The results support a number of important design elements for creating high-spin molecules from metalloporphyrins and the corresponding pi-cation radicals. The
Absence of spin superradiance in resonatorless magnets
β Scribed by V. I. Yukalov; E. P. Yukalova
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 238 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1612-2011
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β¦ Synopsis
A spin system is considered with a Hamiltonian typical
of molecular magnets, having dipole-dipole interactions and a
single-site magnetic anisotropy. In addition, spin interactions
through the common radiation field are included. A fully
quantum-mechanical derivation of the collective radiation rate is
presented. An effective narrowing of the dipole-dipole
attenuation, due to high spin polarization is taken into account.
The influence of the radiation rate on spin dynamics is carefully
analysed. It is shown that this influence is completely
negligible. No noticeable collective effects, such as
superradiance, can appear in molecular magnets, being caused by
electromagnetic spin radiation. Spin superradiance can arise in
molecular magnets only when these are coupled to a resonant
electric circuit, as has been suggested earlier by one of the
authors in Laser Phys. 12, 1089 (2002).
π SIMILAR VOLUMES
We have investigated the use of a "split-sinc" RF pulse to selectively store magnetization from a selected region of a sample, for later recall in imaging or spectroscopy experiments. The pulse sequence is based on an original suggestion by Post et al. (West German Patent No. P3209263.6, 13 March 19
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract The internal interactions in spin systems depend on the magnetic field strength, since the latter perturbs the electronic wave functions. The changes in the interaction tensors are approximately proportional to the applied magnetic field. This effect is experimentally most significant f