About the stability and structure of metallic clusters produced by a LMIS
β Scribed by P. Joyes; J. Van De Walle; C. Colliex
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 347 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0304-3991
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## Abstract A new tridentate ligand, {(3,5βdiβ__tert__βbutylβ2βhydroxybenzyl)amino}acetic acid, has been synthesized. This ligand forms [{Na~4~(H~2~O)~4~(ΞΌβH~2~O)~2~}(Mo~2~O~5~L~2~)~2~] (1), which contains an Na~4~^4+^ cluster cation stabilized by [LMoO~2~(ΞΌβO)MoO~2~L]^2β^, upon reaction with Na~2~
A simple tight-binding type of electronic theory is presented for the size and structural dependence of the ionization energy I,, and cohesive energy EEoh(n) of transition-metal clusters. In agreement with recent experimental results a characteristic structure in I, is obtained for Fe, and Ni,, whic