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Abnormal Reactions of Benzylmagnesium Chloride. II. The Mechanism of the o-Tolyl Rearrangement 1

✍ Scribed by Johnson, John R.

Book ID
118173263
Publisher
American Chemical Society
Year
1933
Tongue
English
Weight
283 KB
Volume
55
Category
Article
ISSN
0002-7863

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## Abstract The rearrangement of __p__‐tolyl acetate in nitrobenzene solution catalysed by aluminium chloride gives the __o__‐hydroxyketone only as rearrangement product. __o__‐Tolyl acetate under the same treatment yields mainly the __para__‐substituted hydroxyketone together with a small amount o