Abnormal osmium tetroxide oxidation of N-methylmorphinan derivatives
โ Scribed by Y.K. Sawa; S. Maeda; M. Adachi
- Book ID
- 103402057
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 395 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4020
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๐ SIMILAR VOLUMES
Osmium tetroxide/N-methylmorpholine-N-oxide oxidation of silyl enol ethers, derived from ketones with either kinetic or thermodynamic regiochemical control, produces a-ketols in good to excellent yields. The search for means to introduce hydroxyl functionality adjacent to carbonyl has led to develo
High levels of asymmetry can be achieved in the osmium tetroxide cis-hydroxylation of olefins by employing (-)-(R,R)-N,N,N',N'-tetramethylcyclohexane-l,2-traos-diamine as a chiral ligand for the osmium. Osmium tetroxide oxidation of olefins is an excellent method for forming vicinal diols under mil