Abnormal micellar effects on reactions of azide and N-alkyl-2-bromopyridinium ions
β Scribed by Bunton, Clifford A.; Cuenca, Angela
- Book ID
- 124050148
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 937 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Reactivities of methyl naphthalene-2-sulfonate, MeONs, and its 6-alkyl derivatives, alkyl=Me, n-C(6)H(13) and n-C(12)H(25), 6-Me-MeONs, 6-Hex-MeONs, and 6-Do-MeONs, respectively, are compared for reactions in cetyl trialkylammonium bromide micelles, n-C(16)H(33)NR(3)Br, R=Me, Et, n-Pr, n-Bu, CTABr,
## Abstract Salt effects on the reactions [Fe(CN)~6~]^4β^ + S~2~O^=^~8~ and [Ru(NH~3~)~5~py]^2+^ + S~2~O have been studied in media of different dielectric constants constituted by mixtures of water with organic cosolvents. It is known that salt and solvent effects are coupled and, consequently, ca