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Ab initio theoretical studies of a novel tungsten dihydrogen complex

✍ Scribed by P.Jeffrey Hay

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 275 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85278-1

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✦ Synopsis

Theoretical studier of H3 bound to W(CO)s(PH& predict a stable q2 complex with equal W-II bonds (2. IS A) and a sl@hlly lengthened (0.79 A) H-H bond. The results M compared with recent experimental studies of the related W(CO),(p-IPI& complex, and the nature of the bonding is discussed.

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