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Ab Initio Study of the S N 2 and E2 Mechanisms in the Reaction between the Cyanide Ion and Ethyl Chloride in Dimethyl Sulfoxide Solution

✍ Scribed by Almerindo, Gizelle I.; Pliego, Josefredo R.


Book ID
126024130
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
46 KB
Volume
7
Category
Article
ISSN
1523-7060

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The rate of the solvent substitution reaction, CoCl 3 S Γ€ +Cl Γ€ YCoCl 4 2Γ€ +S (S-solvent) has been studied by means of stopped flow spectrophotometry in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), and the rate constant k f , and the activation enthalpy D f H p and entropy D f S p have