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Ab initio study of the Lewis acid-catalyzed Diels-Alder reaction of sulfur dioxide with isoprene: regioselectivity and stereoselectivity

✍ Scribed by Suarez, D.; Sordo, T. L.; Sordo, J. A.


Book ID
127248996
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
251 KB
Volume
116
Category
Article
ISSN
0002-7863

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Ab initio study of the effect of CH ···
✍ D. Suárez; R. López; J. González; T. L. Sordo; J. A. Sordo 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 402 KB 👁 3 views

Ab initio calcdations at the MP2/6-31G\*//HF/3-21G\* level have been carried out to study Eels-Alder reactions of 2-substituted-1,3-dienes with s u l h dioxide. The CH ... 0 electrostatic interaction detected in some of the transition structures located could be decisive in the control of the exo/en