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Ab Initio Study of the Energetics of Protonation and Homocomplexed Cation Formation in Systems with Pyridine and Its Derivatives

✍ Scribed by Makowski, Mariusz; Sadowski, Rafał; Augustin-Nowacka, Danuta; Chmurzyñski, Lech

Book ID
126975371
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
101 KB
Volume
105
Category
Article
ISSN
1089-5639

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📜 SIMILAR VOLUMES

Potentiometric studies of cationic heter
Potentiometric studies of cationic heteroconjugation equilibria in systems involving free and protonated pyridine derivatives in dimethyl sulfoxide
✍ Danuta Augustin-Nowacka; Mariusz Makowski; Lech Chmurzyński 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 118 KB

Cationic standard heteroconjugation constants K o f (BHB 1 ) have been determined by potentiometric titration in systems formed by 4-aminopyridinium and 4-methylpyridinium cations with 4-methylpyridine, 2-methylpyridine, and pyridine in dimethyl sulfoxide. The constants, expressed as lgK o f (BHB 1