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Ab Initio Studies on Metal−Metal Interaction and 3 [σ*(d)σ(s)] Excited State of the Binuclear Au(I) Complexes Formed by Phosphine and/or Thioether Ligands

✍ Scribed by Pan, Qing-Jiang; Zhang, Hong-Xing


Book ID
120938762
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
235 KB
Volume
108
Category
Article
ISSN
1089-5639

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## Abstract To explore the metal–metal interaction and spectroscopic properties, the ground‐ and excited‐state structures of [M~2~(dpm)~2~]^2+^ [M = Ag (2), Cu (3), dpm = bis(diphosphanyl)methane] and their solvated species [M~2~(dpm)~2~]^2+^·(MeCN)~2~ were optimized by the MP2 and CIS methods, res