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Ab initio studies on clusters of polar molecules. stability of cyclic versus open-chain trimers of hydrogen fluoride

✍ Scribed by Alfred Karpfen; Anton Beyer; Peter Schuster


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
276 KB
Volume
102
Category
Article
ISSN
0009-2614

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✦ Synopsis


Large-scale ab initio calculations ltavc been lxrfornted on cyclic and openchain trimers of ltydro~cn fluoride iacludin: p.utLl geometry optimization. The cyclic trimcr turned out to be more stdblc by = Z hcal/molc. llquilibrimn _ccometrics and hydropen bond energies are compared with corresponding quantities of(lll')z 2nd of the infinite chin (Lila),. * This work has been supported by the Austrian "Fends zur FZjrderung der wissenschaftlichen Forschung" , Project No. 3669.