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Ab initio spin-coupled description of the reactions CH2(1A1) + H2 .fwdarw. CH4 and CH4 .fwdarw. CH3(2A1') + H

✍ Scribed by Sironi, Maurizio; Cooper, David L.; Gerratt, Joseph; Raimondi, Mario

Book ID
121307608
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
907 KB
Volume
112
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Excess molar volumes of [x1CH3CH2CO2(CH2
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Excess molar volumes at the temperature \(298.15 \mathrm{~K}\) of \(\left[x_{1} \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CO}_{2}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{3}+\right.\) \(x_{2} \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{5} \mathrm{OH}+\left(1-x_{1}-x_{2}\right)\left\{\mathrm{CH}_{

Unimolecular reactions of the isolated i
Unimolecular reactions of the isolated immonium ions CH3CH = NH+C4H9, CH3CH2Ch = NH+C4H9 and (CH3)2C = NH+C4H9
✍ Richard D. Bowen; Alex. W. Colburn; Peter J. Derrick πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 858 KB

The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms