Ab initio SCF study of the ground state electronic structure of SN2+2, SN2, SN2−2, S2N+ and S2N−
✍ Scribed by L. Behera; T. Kar; A.B. Sannigrahi
- Book ID
- 113257066
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 981 KB
- Volume
- 209
- Category
- Article
- ISSN
- 0166-1280
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📜 SIMILAR VOLUMES
SCF–Xα–SW calculations have been carried out for SN, S2N2, and S4N4 as well as the analogous oxides NO and N2O2. The electronic charge distribution of the sulfides is remarkably uniform leading to highly polar SN bonds (∼S+1/2N−1/2) in contrast to the oxides where the NO bonds involve less charge tr
Reaction of cupferron [NH 4 L, L = PhN(O)NO -] with tin(IV), complex 2. The tin centers are heptacoordinated in a pentagonal bipyramidal geometry in the dimeric complex 3. diphenyltin(IV) and dimethyltin(IV) halides yields the cupferronato complexes SnL 4 (1), Ph 2 SnL 2 (2) and These complexes inco
Minimal basis set LCAO SCF calculations on SzN2, (SN)z, and (SN)3 have been carried out. A number of electronic configurations for each species were investigated. Triplet states of SzNz and <SN)= and a quartet state of (SN)3 were found to be lowest in energy at rhis level of calculation. The S2N2 mo