The second largest molecule so far dealt with by ab initio methods is the tetrameric Al^1^ compound [__t__Bu~3~SiAl]~4~. The calculations yielded structure parameters that are in agreement with those of related compounds, and showed that, above all, the lack of π backbonding in the monomer explains
Ab initio investigation of the structures and stabilities of the donor-acceptor complexes H3PBF3 and Me3PBF3
✍ Scribed by Reinhart Ahlrichs; Michael R. Bär; Marco Häser; Ewald Sattler
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 447 KB
- Volume
- 184
- Category
- Article
- ISSN
- 0009-2614
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