Ab Initio Calculations on the Mechanism of the Oxidation of the Hydroxymethyl Radical by Molecular Oxygen in the Gas Phase: A Significant Reaction for Environmental Science

Intermediates and Products of the Hexach

Intermediates and Products of the Hexachlorodisilane Cleavage of Group 14 Element Phosphanes and Amines – Molecular Structure of Di-tert-butyl(trichlorosilyl)phosphane in the Gas Phase Determined by Electron Diffraction and ab Initio Calculations

✍ Wolf-W. du Mont; Lars Müller; Reiner Martens; Paul M. Papathomas; Bruce A. Smart 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 361 KB

Reactions of dialkyl(trimethylsilyl)phosphanes RRЈPSiMe 3 (1: compounds R 3 SnSiCl 3 (19a-c) that decompose providing (R 3 Sn) 2 Si(SiCl 3 ) 2 (18a-c) and nBu 3 SnSi(SiCl 3 ) 3 (20c). R, RЈ = tBu; 3: R, RЈ = iPr; 5: R = iPr, RЈ = tBu) with Si 2 Cl 6 provide stable trichlorosilylphosphanes RRЈPSiCl 3