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Ab initio calculations of hydroxoplatinum compounds: II. Binuclear platinum(IV) superoxo complexes

✍ Scribed by D. A. Pankratov; A. I. Dement’ev; Yu. M. Kiselev

Book ID
110181860
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
244 KB
Volume
53
Category
Article
ISSN
0036-0236

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The geometry dependence of the exchange integrals and the total energies of sulfur-bridged complexes of the types L NiSNiL , L NiS NiL , and 5 5 4 2 4 L NiS NiL is studied by quantum chemical ab initio methods. The linear monobridged 3 3 3 complex is antiferromagnetic, the bi-and triply-bridged com