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Ab initio calculation on thermochemistry of CH3SOxH (x=1–3) and H2SOy (y=2,3)

✍ Scribed by Liming Wang; Jingsong Zhang


Book ID
114141825
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
306 KB
Volume
581
Category
Article
ISSN
0166-1280

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## Abstract Raman spectra of 1,3‐disilabutane (SiH~3~CH~2~SiH~2~CH~3~) as a liquid were recorded at 293 K and as a solid at 78 K. In the Raman cryostat at 78 K an amorphous phase was first formed, giving a spectrum similar to that of the liquid. After annealing to 120 K, the sample crystallized and