✦ LIBER ✦
Ab initio calculation of deuteron quadrupole coupling constants for low-lying rovibrational levels of HD in its X 1Σg+ and B 1Σu+ states
✍ Scribed by J. Vojtík; I. Paidarová; V. Špirko; J. Šavrda; M. Petráš
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 483 KB
- Volume
- 157
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Deuteron quadrupole coupling constants of rovibrational levels of HD in its X 'xl and B '1: states have been calculated from molecular wavefunctions which explicirly describe vibrational motion. The quadrupole coupling constants obtained exhibit significant vibrational and rotational dependence. A marked difference between the X 'x2 and B 'Z: quadrupole hyperfine patterns is predicted. Some aspects for the future theoretical interpretation of the hyperfine structure of laser-induced fluorescence and infrared saturated absorption spectra of diatomic molecules are outlined.