A31P NMR study of ligand substitution in heterometallic Ru/Zn complexes
โ Scribed by G. A. Kostin; A. O. Borodin; S. V. Tkachev; N. V. Kuratieva
- Book ID
- 110170631
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2011
- Tongue
- English
- Weight
- 210 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-4766
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๐ SIMILAR VOLUMES
## Abstract Rhodium(I) complexes containing chiral chelating diphosphines, e.g. __R__,__R__โdipamp [(__R__,__R__)โ1,2โbis(__o__โmethoxyโphenylphenylphosphino)ethane] or __S__,__S__โchiraphos [(2__S__,3__S__)โbis(diphenylphosphino)butane] and a prochiral olefin, e.g. methyl (__Z__)โฮฑโacetamidocinnam
Structural models have been proposed for heterometallic complexes that can be formed in extracts containing Ru anions and M cations (M=Cu, Zn, Co or Ni). Formation of these complexes is accompanied by Ru-O distance increase while the Ru-N distances are unchanged within the determination error. Clear