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A2Σ+–X2Π Bands of18OD

✍ Scribed by A.S-C. Cheung; C.M-T. Chan; K.W-S. Leung; N.S-K. Sze


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
405 KB
Volume
175
Category
Article
ISSN
0022-2852

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✦ Synopsis


The emission spectrum of the A 2 S / -X 2 P (0, 0), (1, 0), and (1, 1) bands of 18 OD has been investigated with a 6.65-m vacuum spectrograph in the wavelength region 290 to 350 nm. The emission spectrum of 18 OD was produced by microwave discharge of D 2 18 O vapor. All 12 branches expected from a 2 S-2 P transition have been observed and assigned. A merged least-squares fit of the measured line positions yielded molecular parameters of the £ Å 0 and 1 levels of both A 2 S / and X 2 P states. Excellent agreement has been obtained between determined molecular parameters and those calculated from isotopic relationships.


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