The trisaccharide b-d-Glcp-(1 3 2)-b-d-Glcp-(1 3 3)-a-d-Glcp-OMe has been investigated by molecular dynamics (MD) simulations and NMR experiments in water. 13 C spinlattice (T 1 ) and spin ± spin (T 2 ) relaxation times, together with 1 H, 13 C NOE data were measured at two magnetic field strengths
✦ LIBER ✦
A1H NMR Spectroscopic Approach to the Unambiguous Determination of Glycosyl Linkage Positions in Oligosaccharides
✍ Scribed by Shuqun Sheng; Robert Cherniak; Herman van Halbeek
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 114 KB
- Volume
- 256
- Category
- Article
- ISSN
- 0003-2697
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## Abstract It is demonstrated that in a case where neither the proton nor the natural‐abundance ^13^C‐satellite spectra of a partially oriented molecule carry enough structural information, one can determine the entire molecular geometry by the combined use of several liquid crystals as solvents.