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A[1,2,3]benzothiadiphospholo [3,2-b]-[1,2,3] benzothiadiphosphole as a further product from the reaction of aryl methyl thioethers with PCl3 and AlCl3

✍ Scribed by Graziano Baccolini; Carmine Antonio Mosticchio; Elisabetta Mezzina; Corrado Rizzoli; Paolo Sgarabotto

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 355 KB
Volume: 4
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.520040403

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✦ Synopsis

Abstract

The title compound 2b was obtained as a minor product in the reaction between a thioanisole and PCl~3~/AlCl~3~. The crystal and molecular structure has been determined by single crystal X‐ray techniques. The compound crystallizes in the space group P 2~1~/c, with α = 9.004(2), b = 13.416(3), c = 11.662(3) Å, and β = 93.1 (1)°. The molecule adoptes a “butterfly” arrangement.

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