A μ-1,1,1,3,3,3 Azide Anion inside a Trigonal Prism of Silver Centers
✍ Scribed by Guo-Cong Guo; Thomas C. W. Mak
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 120 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Layers of face- and edge-sharing trigonal Ag prisms, of which half are filled with azide units, are contained in the novel compound AgN ⋅2 AgNO (see structure). Pendant η -nitrate groups are attached to both sides of each layer.
📜 SIMILAR VOLUMES
The energy barrier to be overcome in anionic 3 + 2 cycloadditions according to (A) (21 and the corresponding cyclo--~~~' 1 ~~H 5 eliminations according to (8) (X = 0, S)[31 should be low since the symmetry of the ~i orbitals is conserved [4+51. The direction of reaction is dictated by the arrangemen
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